- 충방전 과정중 구조가 안정한 Zr이 도핑된 LiCoO2 분말
- ㆍ 저자명
- 김선혜,심광보,안재평,김창삼,Kim. Seon-Hye,Shim. Kwang-Bo,Ahn. Jae-Pyoung,Kim. Chang-Sam
- ㆍ 간행물명
- 한국세라믹학회지
- ㆍ 권/호정보
- 2008년|45권 3호|pp.167-171 (5 pages)
- ㆍ 발행정보
- 한국세라믹학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
Zirconium-doped $Li_{1.1}Co_{1-x}Zr_xO_2(0{leq}x{leq}0.05)$ powders as cathode materials for lithium ion batteries were synthesized using an ultrasonic spray pyrolysis method. Cyclic voltammetry and cyclic stability tests were performed, and the changes of microstructure were observed. The solubility limit of zirconium into $Li_{1.1}CoO_2$ was less than 5 mol%, and monoclinic $Li_2ZrO_3$ phase was formed above the limit. The Zr-doping suppressed the grain growth and increased the lattice parameters of the hexagonal $LiCoO_2$ phase. The Zr-dopiong of 1mol% resulted in the best cyclic performance in the range of $3.0{sim}4.3V$ at 1C rate (140 mA/g); the initial discharge capacity decreased from 158 mAh/g to 60 mAh/g in the undoped powder, while from 154 mAh/g to 135 mAh/g in the Zr-doped powder of 1 mol% after 30 cycles. The excellent cycle stability of Zr-doped powder was due to the low polarization during chargedischarge processes which resulted from the delayed collapse of the crystal structure of the active materials with Zr-doping.