- (40-x)BaO⋅xFe2O3⋅60P2O5 유리의 Fe3+이온에 관한 전자스핀공명 연구
- ㆍ 저자명
- 강은태,Kang. Eun-Tae
- ㆍ 간행물명
- 한국세라믹학회지
- ㆍ 권/호정보
- 2008년|45권 3호|pp.179-184 (6 pages)
- ㆍ 발행정보
- 한국세라믹학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
(40-x)BaO${cdot}xFe_2O_3{cdot}60P_2O_5$ glasses with $5{leq}x{leq}35mol%$ were investigated by ESR spectroscopy. Two resonances observed near g=2.0 and g=4.3. The line at g=4.3 disappeared with the increase of the $Fe_2O_3$ content. The resonance at $g{approx}2.0$ displayed characteristic signal consisting of superposed extremely broad and narrow components. The broader one indicates the presence of the association of two or more $Fe^{3+}$ ions, antiferromagnetically and the narrow one is related to the microclusters involving iron ions. Temperature dependence of the ESR integrated intensity revealed short-range antiferromagnetic character for $x{geq}15mol%$.