In this paper, we proposed effective algorithm that do Availability of communication network account using total probability formula. Use path tracing method about PSTN linked with MSC in WCDMA considering occasion that do not consider mobility of terminal and Availability did account. First, express minimum path series gathering by structure function after network that do modeling by stochastic graph for communication network saves all minimal path sets between particular two abutments and we gain Availability value in angular variable after express structure function by Boolean operation form and Availability between two abutments did account.