Two types of conductive materials are selected and their applicable properties are investigated so as to give the capability of self-diagnosis of fracture in composite mortar, concrete and reinforced concrete. In this study, for giving selfdiagnosis capability, the powder of cokes and milled carbon fiber as conductive materials are selected and intermixed with mortar, concrete and reinforced concrete. After examining change in the value of electric resistance before and after the occurrence of cracks at each flexural load-stage in composite mortar, concrete or reinforced concrete, the relationships of each factors (electric resistance, crack and flexural load) are analyzed. As the results, it can be recognized that conductive materials with powder of cokes and milled carbon fiber can be applied for self-diagnosis of flexural fracture in composite mortar, concrete and reinforced concrete specimen.