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In Situ Crosslinked Ionic Gel Polymer Electrolytes for Dye Sensitized Solar Cells
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  • In Situ Crosslinked Ionic Gel Polymer Electrolytes for Dye Sensitized Solar Cells
  • In Situ Crosslinked Ionic Gel Polymer Electrolytes for Dye Sensitized Solar Cells
저자명
Shim. Hyo-Jin,Kim. Dong-Wook,Lee. Chang-Jin,Kang. Yong-Ku,Suh. Dong-Hack
간행물명
Macromolecular research
권/호정보
2008년|16권 5호|pp.424-428 (5 pages)
발행정보
한국고분자학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

We prepared an ionic gel polymer electrolyte for dye-sensitized solar cells (DSSCs) without leakage problem. Triiodide compound (BTDI) was synthesized by the reaction of benzene tricarbonyl trichloride with diethylene glycol monotosylate and subsequent substitution of tosylate by iodide using NaI. Bisimidazole was prepared by the reaction of imidazole with the triethylene glycol ditosylate under strongly basic condition provided by NaH. BTDI and bisimidazole dissolved in an ionic liquid were injected into the cells and permeated into the $TiO_2$ nanopores. In situ crosslinking was then carried out by heating to form a network structure of poly(imidazolium iodide), thereby converting the ionic liquid electrolytes to a gel or a quasi-solid state. A monomer (BTDI and bisimidazole) concentration in the electrolytes of as low as 30 wt% was sufficient to form a stable gel type electrolyte. The DSSCs based on the gel polymer electrolytes showed a power conversion efficiency of as high as 1.15% with a short circuit current density of $5.69;mAcm^{-2}$, an open circuit voltage of 0.525 V, and a fill factor of 0.43.