COMS (Communication, Ocean and Meteorological Satellite) is a geostationary satellite and has been developing by KARI for communication, ocean and meteorological observations. It will be launched by ARIANE 5. Ka-band components are installed on South panel, where single solar array wing is mounted. Radiators, embedded heat pipes, external heat pipe, insulation blankets and heaters are utilized for the thermal control of the satellite. The Ka-band payload section is divided several areas based on unit operating temperature in order to optimize radiator area and maximize heat rejection capability. Other equipment for sensors and bus are installed on North panel. The ocean and meteorological sensors are installed on optical benches on the top floor to decouple thermally from the satellite. During the transfer orbit operation, satellite will be under severe thermal environments due to low dissipation of components, satellite attitudes and LAE(Liquid Apogee Engine) firing. This paper presents temperature and heater power prediction and validation of thermal control design during transfer orbit operation.