In this study, we conducted a comprehensive study to analyze the environmental behavior of airborne Ni for the proper establishment of basic control tactics based on the metal concentration data sets collected from the major cities in Korea for the 14 year period(1991 through 2004). The mean concentration of Ni determined from all cities during the entire study period varied from as little as 7.38+6.70 ng $m^3$(Won Ju) to the maximum of 41.4+26.2 ng $m^3$ in a highly industrialized city of An San. However, the mean concentrations of Ni from most cities generally fell in the range of 10 to 20 ng $m^3$. When the Ni concentration data in all cities are compared between the former half(1991 to 1997) and the latter half period(1998 to 2004), a reduction in its concentration levels was seen dominantly between the two study period. Comparison of seasonal patterns generally indicated the enhanced concentrations of Ni during spring/winter relative to summer/fall term. The overall results of this study suggest that the source processes of Ni are diverse enough to exhibit moderately diverse patterns between different cities. Considering that relative enhancement in Ni levels is observed from most of industrial and/or large scale cities, a development of adequate control tactics for Ni is highly desirable.