- 가는줄돌쩌기 알칼로이드 성분의 분리 및 산화적 특성
- Isolation and Oxidation Characteristics of Alkaloids of Aconitum volubile
- ㆍ 저자명
- 허경희,이정규,Heo. Kyong-Hee,Lee. Chung-Kyu
- ㆍ 간행물명
- 생약학회지
- ㆍ 권/호정보
- 2008년|39권 2호|pp.127-134 (8 pages)
- ㆍ 발행정보
- 한국생약학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
From the under ground part of Aconitum volubile Pall. (Ranunculaceae),seven nor- or di-terpenoid alkaloids were isolated and identified by NMR spectra and mass spectrum. The alkaloids were three $C_{19}$-norditerpenoid alkaloids such as isotalatizidine, altaconitine and vilmorrianine A, and four $C_{20}$-diterpenoid alkaloids such as 12-epidehydronapelline, 12-epinapelline, songoramine and songorine. Some of the isolated diterpenoid alkaloids were subjected to oxidation reaction with active $MnO_2$ and oxoammonium salt. The results were C-12 oxidation(ketone formation) and N-dealkylation in veatchin-type and decomposition to non-alkaloidal compounds in atisine-type ajaconine.