In the rocket preburner, oxidizer-rich combustion with liquid oxygen and kerosene is very challenging work. The key factor of stable flame is good mixing and that is controlled by the injector performance. We have studied spray characteristics of the oxidizer-rich rocket preburner injector in high pressure environments. The injector is composed of fuel orifices, oxidizer orifices and cooling skirt with liquid oxygen. By using this apparatus, we have taken photographs and measured Sauter mean diameter with changing ambient pressure from 0 to 30 kgf/cm2[g]. Droplet diameter is measured by the image processing technique. From the test results, we could understand spray characteristics of the oxidizer-rich preburner injector and this result could be applied to the development of the oxidizer rich preburner system.