The improvement of cooling ability for the air conditioner is the most efficient method of application of its system. Therefore, this study has been investigated the improvement of cooling ability for the air conditioner using automotive by attached of a thermoelectric module. According to the result of test, capacity of the thermoelectric module make temperature range from $-75^{circ}C$ to $+300^{circ}C$ possible to cooling and exothermic. In addtion to, the reduction effect of energy revealed and the effect of liquid hammer remained with safety by attached the thermoelectric module. It was found that the air conditioner system by attached thermoelectric module have better cooling ability than the air conditioner system of existing vehicle.