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Solid state MAS NMR Investigation on the Local Structures of xV2O5-B2O3-yNa2O Glasses
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  • Solid state MAS NMR Investigation on the Local Structures of xV2O5-B2O3-yNa2O Glasses
  • Solid state MAS NMR Investigation on the Local Structures of xV2O5-B2O3-yNa2O Glasses
저자명
Kim. Sun-Ha,Han. Oc-Hee,Kang. Jae-Pil,Song. Seung-Ki
간행물명
Bulletin of the Korean Chemical Society
권/호정보
2009년|30권 3호|pp.608-612 (5 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The local structures of the boron and vanadium sites in the ternary glass $xV_2O_5-B_2O_3-yNa_2O$ were studied by $^{11}B;and;^{51}V$ magic angle spinning (MAS) nuclear magnetic resonance (NMR). With increasing x, the mole ratios of the $BO_3;and;BO_4$ structures were enhanced, as were the quadrupole asymmetry parameters for the $BO_3$ structures, while the quadrupole coupling constants for the sites were reduced. However, the opposite trends were observed with increasing y, implying that $V_2O_5$ and $Na_2O$ play opposite roles. The $VO_4,;VO_5;and;VO_6$ structures with all oxygens bonded to the vanadium neighbors were identified. Vanadiums bonded to the greater number of oxygens were more populated at higher contents of $Na_2O;and;V_2O_5$. In addition, the $VO_4$ structures with at least one oxygen bonded to boron instead of vanadium were detected at low $Na_2O$ contents. The electron densities of various vanadium oxide structures were affected by the weight densities and vanadium ion densities. The $VO_4$ structures were more likely to be vanadium oxide structures right next to $V4^{+}$ ions.