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Sorbent Characteristics of Montmorillonite for Ni2+Removal from Aqueous Solution
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  • Sorbent Characteristics of Montmorillonite for Ni2+Removal from Aqueous Solution
  • Sorbent Characteristics of Montmorillonite for Ni2+Removal from Aqueous Solution
저자명
Ijagbemi. Christianah Olakitan,Kim. Dong-Su
간행물명
Environmental engineering research
권/호정보
2009년|14권 1호|pp.26-31 (6 pages)
발행정보
대한환경공학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Sorption of $Ni^{2+}$ in aqueous solution was studied using montmorillonite. The experimental and equilibrium data fitted well to the Langmuir isotherm model. From the kinetics data for nickel sorption onto montmorillonite, the diffusion of $Ni^{2+}$ inside the clay particles was the dorminant step controlling the sorption rate and as such more important for $Ni^{2+}$ sorption than the external mass transfer. $Ni^{2+}$ was sorbed due to strong interactions with the active sites of the sorbent and the sorption process tends to follow the pseudo second-order kinetics. Thermodynamic parameters (${Delta}G^{circ},;{Delta}H^{circ},;{Delta}S^{circ}$) indicated a non spontaneous and endothermic adsorption process while the positive low value of the entropy change suggests low randomness of the solid/solution interface during the uptake of $Ni^{2+}$ by montmorilionite. Heavy metals such as $Ni^{2+}$ in aqueous bodies can effectively be sorbed by montmorillonite.