This paper attempts to develop an algorithm which optimizes the electric field through the so-called NURB(Non-Uniform Rational B-spline) curve in order to improve the insulation capacity. In particular, the NURB curve is a kind of interpolation curve that can be expressed by a few variables. The electric field of a conductor is computed by Charge Simulation Method(CSM) while that of a spacer by Surface Charge Method(SCM); this mixed calculation method is adopted for the electric field optimization. For calculation of the initial and optimal shapes, the Gauss-Newton method, which is quite easy to formulate and has slightly faster convergence rate than other optimization techniques, was used. The tangential electric field, the total electric field, and the product of the tangential electric field and area (Area Effect) were chosen as the optimization objective function by the average value of electric field for the determined initial shape.