Disk grinding was often applied to deburring process in order to enhance the final product quality. Inherent chamfering capability of the flexible disk grinding process in the early stage was analyzed with respect to various process parameters including workpiece length, wheel speed, depth of cut and feed. Initial chamfered edge defined as arc zone was characterized with local radius of curvature. Averaged radius and arc zone ratio was well evaluated using neural network system. Additional neural network analysis adding workpiece length showed enhance performance in predicting arc zone ratio and curvature radius with reduced error rate. A process condition design parameter was estimated using remaining input and output parameters with the prediction error rate lower than 2.0% depending on the relevant input parameter combination and neural network structure composition.