- 냉 음극 형광 램프용 Y2O3:Eu3+ 적색 형광체에 대한 이종 Flux 혼합첨가의 영향
- ㆍ 저자명
- 구자인,김상문,신학기,박홍채,윤석영,Goo. Ja-In,Kim. Sang-Moon,Shin. Hag-Ki,Hong. Hong-Chae,Yoon. Seog-Young
- ㆍ 간행물명
- 한국재료학회지
- ㆍ 권/호정보
- 2009년|19권 3호|pp.163-168 (6 pages)
- ㆍ 발행정보
- 한국재료학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
$Eu^{3+}$-doped $Y_2O_3$ red phosphor was synthesized in a flux method using the chemicals $Y_2O_3,;Eu_2O_3,;H_3BO_3$ and $BaCl_2{cdot}2H_2O$. The effect of a flux addition on the preparation of $Y_2O_3:Eu_{3+}$ red phosphor used as a cold cathode fluorescence lamp was investigated. $H_3BO_3$ and $BaCl_2{cdot}2H_2O$ fluxes were used due to their different melting points. The crystallinity, thermal properties, morphology, and emission characteristics were measured using XRD, TG-DTA, SEM, and a photo-excited spectrometer. Under UV excitation of 254 nm, $Eu_2O_3$ 3.7 mol% doped $Y_2O_3$ exhibited a strong narrow-band red emission, peaking at 612 nm. From this result, the phosphor synthesized by firing $Y_2O_3$ with 3.7 mol% of $Eu_2O_3$, 0.25 mol% of $H_3BO_3$ and 0.5 mol% of $BaCl_2{cdot}2H_2O$ fluxes at $1400^{circ}C$ for 2 hours had a larger particle size of $4{mu}m$ on average compared to the phosphor of the $H_3BO_3$ flux alone. In addition, a phosphor synthesized by the two fluxes together had a rounder corner shape, which led to the maximum emission intensity.