Direct numerical simulations(DNS) were performed for the prediction of transient buoyant jet diffusion flames where the Froude numbers(Fr) are 5 and 160, respectively. The thermodynamic and transport properties were evaluated using CHEMKIN package to enhance the prediction performance of the DNS code. The simulated buoyant jet diffusion flame of Fr=5 and 160 showed the transient, dynamic motion well. It was identified that the buoyant jet flames were flickered periodically, and the simulated flickering frequency of the jet diffusion flame of Fr=5 was 12.5Hz, which was in good agreement with the experimental results. The flamelet structures of the buoyant jet diffusion flames could be well understood by comparing the scalar dissipation rates(SDR) and the heat release rates(HRR) of the flames. It was found that the SDR was strongly coupled with the HRR in the buoyant jet diffusion flames.