The object of this study is to develop new examination technique for detecting debond in adhesive interface of different kinds of materials. Ultrasonic signal was modeled by theoretically analyzing ultrasonic propagation phenomenon of the adhesive interface and debonding interface. The test method using the phase reversal of the debonding interface applied to the FRP/Rubber test block. Aluminum/Rubber test block with the flat bottom hole was manufactured to evaluate quantitatively the minimum detection ability of defects. The pulse echo reflection method and the phase reversal method were mutually compared and it was estimated that the phase reversal method could detect the debond on the basis of the theoretically predicted ultrasonic signal and ultrasonic test data.