- 금속열환원법에 의한 니오븀 분말제조시 환원제의 영향
- ㆍ 저자명
- 황선호,윤재식,김병일,Hwang. Sun-Ho,Yoon. Jae-Sik,Kim. Byung-Il
- ㆍ 간행물명
- 한국표면공학회지
- ㆍ 권/호정보
- 2009년|42권 4호|pp.186-189 (4 pages)
- ㆍ 발행정보
- 한국표면공학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
In this study, niobium powder was made from potassium heptafluoroniobite($K_2NbF_7$) using sodium(Na) as a reductant and KCl, KF as a diluent based on the hunter metallothermic reduction method. The excesses of reductant were varied from 0%, 3%, 5% and 7%. When 7% excess of sodium was used, the un-reacted sodium remained in the reacted product. The niobium powder has been achieved by reducing 50 g of $K_2NbF_7$ with 5% sodium excess in a charge at a reduction temperature of $850^{circ}C$. The proportion of fine fraction decreased appreciably and the yield of niobium powder improved from 65% to 85% with the increase of sodium excess. The average particle size of niobium powder is improved from 0.2 microns to 0.3 microns in the 5% excess sodium.