The Rayleigh-Taylor instability, the bubble rising in both partially and fully filled containers and the droplet splash are simulated by an in-house solution code(PowerCFD), which are typical benchmark problems among multiphase flows with material interface due to density difference. The present method(code) employs an unstructured cell-centered method based on a conservative pressure-based finite-volume method with interface capturing method(CICSAM) in a volume of fluid(VOF) scheme for phase interface capturing. The present results are compared with other numerical solutions found in the literature. It is found that the present method simulates efficiently and accurately complex free surface flows such as multiphase flows with material interface due to both density difference and instability.