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Preparation and Acid Dye Adsorption Behavior of Polyurethane/Chitosan Composite Foams
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  • Preparation and Acid Dye Adsorption Behavior of Polyurethane/Chitosan Composite Foams
  • Preparation and Acid Dye Adsorption Behavior of Polyurethane/Chitosan Composite Foams
저자명
Lee. Ho-Cheon,Jeong. Young-Gyu,Min. Byung-Gil,Lyoo. Won-Seok,Lee. Sang-Cheol
간행물명
Fibers and polymers
권/호정보
2009년|10권 5호|pp.636-642 (7 pages)
발행정보
한국섬유공학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

We prepared a series of polyurethane(PU)/chitosan composite foams with different chitosan content of 5~20 wt% and investigated their adsorption performance of acid dye (Acid Violet 48) in aqueous solutions with various dye concentrations and pH values. It was observed that PU/chitosan composite foams exhibited well-developed open cell structures. Dye adsorption capacities of the composite foams increased with the increment of chitosan content in composite foams, because amine groups of chitosan serve as the binding sites for sulfonic ions of acid dyes in aqueous solutions. In addition, dye adsorption capacities of composite foams were found to increase with decreasing the pH value, which stems from the fact that the enhanced chemisorption between protonated amine groups of chitosan and sulfonic ions of acid dye is available in acidic solutions. The dye adsoption kinetics and equilibrium isotherm of the composite foams were well described with the pseudosecond order kinetic model and Langmuir isotherm model, respectively. The maximum adsorption capacity ($q_{max}$) for the PU/chitosan composite foams with 20 wt% chitosan content is evaluated to be ca. 30 mg/g.