기관회원 [로그인]
소속기관에서 받은 아이디, 비밀번호를 입력해 주세요.
개인회원 [로그인]

비회원 구매시 입력하신 핸드폰번호를 입력해 주세요.
본인 인증 후 구매내역을 확인하실 수 있습니다.

회원가입
서지반출
Novel Synthesis of Mannosamine Conjugated Magnetic Nanoparticles for Purification and Stabilization of Human Lysosomal $eta$-mannosidase
[STEP1]서지반출 형식 선택
파일형식
@
서지도구
SNS
기타
[STEP2]서지반출 정보 선택
  • 제목
  • URL
돌아가기
확인
취소
  • Novel Synthesis of Mannosamine Conjugated Magnetic Nanoparticles for Purification and Stabilization of Human Lysosomal $eta$-mannosidase
  • Novel Synthesis of Mannosamine Conjugated Magnetic Nanoparticles for Purification and Stabilization of Human Lysosomal $eta$-mannosidase
저자명
Samra. Zahoor Qadir,Athar. Muhammad Amin
간행물명
Biotechnology and bioprocess engineering
권/호정보
2009년|14권 5호|pp.651-661 (11 pages)
발행정보
한국생물공학회
파일정보
정기간행물|ENG|
PDF텍스트
주제분야
기타
이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
서지반출

기타언어초록

Human $eta$-mannosidase (MANB) was purified to homogeneity directly from lysosomes by using mannosamine conjugated magnetic ($Fe_3O_4$) nanoparticles, DE-52 cellulose, and sephadex G-200 chromatography. $Fe_3O_4$ nanoparticles were synthesized and utilized ammonia to attach the amino group on the nanoparticles. The particles were covalently attached with Dmannosamine by cross linker glutaraldehyde and confirmed by FTIR spectroscopy. In FTIR analysis, the peaks appeared at 2,356.6 $cm^{-1}$ for -N = CH linkage and at 3,378.4 $cm^{-1}$, 3,664.9 $cm^{-1}$ for -OH groups confirmed the conjugation of D-mannosamine with $Fe_3O_4$ nanoparticles. Results showed a single band of 97 kDa of purified MANB in SDS-PAGE. The isoelectric point was 4.5 and the $K_m$ and Vmax values were 2.51 mM and $0.315;{mu}M/min/mg$, respectively. The purification fold was 329 with 68% yield. The optimal activity was at pH 5.0 and 75% activity was stable in 20% glycerol at $4^{circ}C$. The enzyme activity was inhibited by $Ni^{2+}$, $Zn^{2+}$, $Cd^{2+}$, $Cu^{2+}$, $Mo^{2+}$, $Ag^{+1}$, iodoacetate, SDS, DMF, DMSO, ethanol, and acetone; slightly reduced by $Pb^{2+}$, $Co^{2+}$, EDTA, DTT, and $eta$-mercaptoethanol. The activity was not affected by $Mg^{2+}$, $Mn^{2+}$, $Sn^{2+}$, $Ca^{2+}$, $Fe^{3+}$, PMSF, Triton X-100, D-mannosamine, D-mannose, D-mannitol, D-glucose, and D-fructose. The homogeneity of MANB enzyme was further confirmed by 2D-PAGE and immunoblot. This is the first novel report of conjugation of D-mannosamine with $Fe_3O_4$ nanoparticles for purification of human MANB enzyme.