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CORROSION BEHAVIOR OF NI-BASE ALLOYS IN SUPERCRITICAL WATER
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  • CORROSION BEHAVIOR OF NI-BASE ALLOYS IN SUPERCRITICAL WATER
  • CORROSION BEHAVIOR OF NI-BASE ALLOYS IN SUPERCRITICAL WATER
저자명
Zhang. Qiang,Tang. Rui,Li. Cong,Luo. Xin,Long. Chongsheng,Yin. Kaiju
간행물명
Nuclear engineering and technology : an international journal of the Korean Nuclear Society
권/호정보
2009년|41권 2호|pp.107-112 (6 pages)
발행정보
한국원자력학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Corrosion of nickel-base alloys (Hastelloy C-276, Inconel 625, and Inconel X-750) in $500^{circ}C$, 25 MPa supercritical water (with 10 wppb oxygen) was investigated to evaluate the suitability of these alloys for use in supercritical water reactors. Oxide scales formed on the samples were characterized by gravimetry, scanning electron microscopy/energy dispersive spectroscopy, X-ray diffraction, and X-ray photoelectron spectroscopy. The results indicate that, during the 1000 h exposure, a dense spinel oxide layer, mainly consisting of a fine Cr-rich inner layer ($NiCr_2O_4$) underneath a coarse Fe-rich outer layer ($NiFe_2O_4$), developed on each alloy. Besides general corrosion, nodular corrosion occurred on alloy 625 possibly resulting from local attack of ${gamma}"$ clusters in the matrix. The mass gains for all alloys were small, while alloy X-750 exhibited the highest oxidation rate, probably due to the absence of Mo.