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서지반출
Facile Synthesis of Dendritic-Linear-Dendritic Materials by Click Chemistry
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  • Facile Synthesis of Dendritic-Linear-Dendritic Materials by Click Chemistry
  • Facile Synthesis of Dendritic-Linear-Dendritic Materials by Click Chemistry
저자명
Lee. Jae-Wook,Han. Seung-Choul,Kim. Byoung-Ki,Lee. Un-Yup,Sung. Sae-Reum,Kang. Hwa-Shin,Kim. Ji-Hyeon,Jin. Sung-Ho
간행물명
Macromolecular research
권/호정보
2009년|17권 7호|pp.499-505 (7 pages)
발행정보
한국고분자학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
서지반출

기타언어초록

General, fast, and efficient stitching methods are presented for the synthesis of Fr$acute{e}$chet-type dendrimers with linear units at a core, as a preliminary investigation for the synthesis of dendritic-linear-dendritic materials. The synthetic strategy involved an inexpensive, 1,3-dipolar, cycloaddition reaction between an alkyne and an azide in the presence of the Cu(I) species, which is known as the best example of click chemistry. The linear core building blocks, 1,7-octadiyne and 1,6-diazidohexane, were chosen to serve as the alkyne and azide functionalities for dendrimer growth via click reactions with the azide and alkyne-dendrons, respectively. These two building blocks were employed together with the azide- and alkyne-functionalized Fr$acute{e}$chet-type dendrons in a convergent strategy to synthesize two kinds of Fr$acute{e}$chet-type dendrimers with different linear core units. This comparative efficiency of the click methodology supports the fast and efficient synthesis of dendritic-linear-dendritic materials with the tailor made core unit.