The operating range of HCCI engine is narrow due to excessive rate of pressure rise on high load. The fuel stratification is proposed to solve the problem. The purpose of this study is to gain a better understanding of the effects of fuel stratification on reducing the pressure-rise rate at high load in HCCI combustion and to investigate that the operating range is expanded for fuel stratification in the preceding condition of initial temperature and equivalence ratios. The engine is fueled with Di-Methyl Ether (DME) which has unique 2-stage heat release. The computations were conducted using SENKIN application of the CHEMKINll kinetics rate code. Calculation result shows that proper fuel stratification prolongs combustion duration and reduce pressure rise rate.