Reflection properties, such as specular reflection and diffuse reflection, are very important optical properties for the reflector, which has high reflectance in the display and architecture industry. Calcite is lowcost, nontoxic, and stable over a wide temperature range. Therefore, it is one of the most widely using fillers in many industries and has some advantages over titania as a filler to improve reflectance. However, optical properties, especially those of ceramic-filled composites, have not been analyzed. We studied the reflectance of calcite composites with their surface roughness. The reflectance of the composites was determined using a UV-visible spectrometer. The surface morphology and the micro-structure of the composites were investigated by atomic force microscope. The reflectance of the composites was improved by increasing the content of calcite in the calcite-frit composite. The reflectance is related with the surface roughness in the composites. However, the reflectance depends on the calcite contents in materials with similar surface roughness.