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Effect of Hot Pressing/Melt Mixing on the Properties of Thermoplastic Polyurethane
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  • Effect of Hot Pressing/Melt Mixing on the Properties of Thermoplastic Polyurethane
  • Effect of Hot Pressing/Melt Mixing on the Properties of Thermoplastic Polyurethane
저자명
Lee. Young-Hee,Kang. Bo-Kyung,Kim. Han-Do,Yoo. Hye-Jin,Kim. Jung-Soo,Huh. Jae-Ho,Jung. Young-Jin,Lee. Dong-Jin
간행물명
Macromolecular research
권/호정보
2009년|17권 8호|pp.616-622 (7 pages)
발행정보
한국고분자학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
서지반출

기타언어초록

In-depth understanding of the influence of hot pressing and melt processing on the properties of thermoplastic polyurethane (TPU) is critical for effective mechanical recycling of TPU scraps. Therefore, this study focused on the effects of hot pressing and melt mixing on molecular weight (MW), polydispersity index (PDI), melt index (MI), characteristic IR peaks, hardness, thermal degradation and mechanical properties of TPU. The original TPU pellet (o-TPU) showed two broad peaks at lower and higher MW regions. However, four TPU film samples, TPU-0 prepared only by hot pressing of o-TPU pellet and TPU-1, TPU-2 and TPU-3 obtained by hot pressing of melt mixed TPUs (where the numbers indicate the run number of melt mixing), exhibited only a single peak at higher MW region. The TPU-0 film sample had the highest $M_n$ and the lowest PDI and hardness. The TPU-1 film sample had the highest $M_w$ and tensile modulus. As the run number of melt mixing increased, the peak-intensity of hydrogen bonded C=O stretching increased, however, the free C=O peak intensity, tensile strength/elongation at break and average MW decreased. All the samples showed two stage degradations. The degradation temperatures of TPU-0 sample (359 $^{circ}C$ and 394 $^{circ}C$)were higher than those of o-TPU (342 $^{circ}C$ and 391 $^{circ}C$). While all the melt mixed samples degraded at almost the same temperature (365 $^{circ}C$ and 381 $^{circ}C$). The first round of hot pressing and melt mixing was found to be the critical condition which led to the significant changes of $M_n$/$M_w$/PDI, MI, mechanical property and thermal degradation of TPU.