Emergent requests or urgent information among enterprises require their intimate collaboration in B2B EC (electronic commerce). This paper analyzes the needs of intimate cooperation of distributed EC systems in terms of business contracts and presents an active rule-based methodology of close cooperation among EC systems and an active rule component to support it. Since the rule component provides high level rule patterns and event-based immediate processing, system administrators and programmers can easily program and maintain intimate cooperation of distributed EC systems independently to the application logic. The proposed active rule component facilitates HTTP protocol. Its prototype is implemented in B2B EC environment and evaluated using basic trigger facility of a commercial DBMS.