Reactivity of RhCp* Complexes Containing Labile Ligands toward Potential Linking Ligands Containing Terminal Thiophene or Furan Rings:Preparation and Structures of [Cp*Rh(L1)Cl2], [Cp*Rh(η2-NO<S

Reactivity of RhCp* Complexes Containing Labile Ligands toward Potential Linking Ligands Containing Terminal Thiophene or Furan Rings:Preparation and Structures of [Cp^*Rh(L¹)Cl₂], [Cp^*Rh(η²-NO
Reactivity of RhCp* Complexes Containing Labile Ligands toward Potential Linking Ligands Containing Terminal Thiophene or Furan Rings:Preparation and Structures of [Cp^*Rh(L¹)Cl₂], [Cp^*Rh(η²-NO

ㆍ 저자명: Lee. Kyung-Eun,Lee. Soon-W.
ㆍ 간행물명: Bulletin of the Korean Chemical Society
ㆍ 권/호정보: 2010년|31권 12호|pp.3600-3604 (5 pages)
ㆍ 발행정보: 대한화학회
ㆍ 파일정보: 정기간행물|ENG|
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ㆍ 주제분야: 기타

이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.

서지반출

기타언어초록

Rhodium(III)-$Cp^*$ complexes containing labile ligands, $[Cp^*RhCl_2]_2$, [$Cp^*Rh({eta}^2-NO_3)$(OTf)], and $[Cp^*Rh(OH_2)_3](OTf)_2$, reacted with potential linking ligands [$L^1$ = (2-thiophene)-CH=N-N=CH-(2-thiophene); $L^2$ = (2-furan)-CH=N-N=CH-(2-furan)] to give two molecular compounds, [$Cp^*Rh(L^1)Cl_2$] (1) and [$Cp^*Rh({eta}^2-NO_3)(L^1)$]$(OTf){cdot}CH_2Cl_2$ ($2{cdot}CH_2Cl_2$), and one 1-dimensioanl coordination polymer, ${[Rh(L^2)]{cdot}(OTf)}_{infty}$ (3). Whereas one imine nitrogen atom within the ligand is coordinated to the Rh metal in compounds 1 and 2, both nitrogen atoms are bound to two neighboring Rh metals in compound 3 to lead to a 1-D chain polymer.

키워드

Rhodium-$Cp^*$Bis(thipohene)Bis(furan)1-D Chain Rhodium coordination polymer

다운URL