It has already been 17 years since the first implementation of the Korean College Scholastic Ability Test (CSAT). Having been administered so many CSAT tests including practice tests, criticisms have been made against CAST tests being stuck to the same pattern and focusing mainly on knowledge-based items. To address this issue, we analyzed the chemistry items of the Japanese National Center Test for University Admissions (NCTUA) administered in January of 2009 with regard to content factors, behavioral domains, item types, and noted any peculiarities in comparison to CSAT. Also, we estimated the predicted percentage of correct answers from the perspectives of Korean candidates to arrive at implications for chemistry items of CSAT.