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Enhanced Electrochemical Property of Surface Modified Li[Co1/3Ni1/3Mn1/3]O2 by ZrFx Coating
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  • Enhanced Electrochemical Property of Surface Modified Li[Co1/3Ni1/3Mn1/3]O2 by ZrFx Coating
  • Enhanced Electrochemical Property of Surface Modified Li[Co1/3Ni1/3Mn1/3]O2 by ZrFx Coating
저자명
Yun. Su-Hyun,Park. Yong-Joon
간행물명
Bulletin of the Korean Chemical Society
권/호정보
2010년|31권 2호|pp.355-359 (5 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

A $Li[Co_{1/3}Ni_{1/3}Mn_{1/3}]O_2$ cathode was modified by applying a $ZrF_x$ coating. The surface-modified cathodes were characterized by XRD, SEM, EDS, TEM techniques. XRD patterns of $ZrF_x$-coated $Li[Co_{1/3}Ni_{1/3}Mn_{1/3}]O_2$ revealed that the coating did not affect the crystal structure of the parent powder. SEM and TEM images showed that $ZrF_x$ nano-particles were formed as a coating layer, and EDS data confirmed that $ZrF_x$ distributed uniformly on the surface the powder. Capacity retention of coated samples at high C rates was superior to that of pristine sample. However, as the coating concentration increases beyond the optimum concentration, the rate capability was deteriorated. Whereas, as the increase of coating concentration to 2.0 wt %, the cyclic performances of the electrodes under the severe conditions (high cut-off voltage, 4.8 V, and high measurement temperature, $55^{circ}C$) were improved considerably.