Spectral library is a database that archives spectral reflectance and related metadata of earth surface materials. Spectral library plays important role to assist analyzing several types of remote sensor data, to determine suitable wavelength band for detecting a certain material, and to classify hyperspectal image data. This paper describes the structure and content of a spectral library that is suitable for the environment of the Korea peninsula while existing spectral libraries have certain limitations to apply for surface materials covering the region. We designed a spectral library that includes vegetation and man-made materials indigenous to the region. The spectral library also includes spectra of mineral and rock, soil, liquid, and some man-made materials from existing spectral libraries. Newly augmented spectra of vegetation and man-made materials were obtained by spectral measurements in laboratory and field. The spectral library viewer was developed to increase efficiency of usage and searching.