In this paper, a new algorithm of optimal Volt/Var Control is proposed using Volt/Var control for the Distribution Automation System (DAS) with Distributed Generation (DG) based on the modeling of the distributed load and the distributed current. In the proposed, algorithm based on the modeling of the distributed load and the distributed current are estimated from constants of four terminals using the measurement of the current and power factor from a Feeder Remote Terminal Unit (FRTU) and DG data from RTU for DG. For the optimal Volt/Var Control, the gradient method is applied to find optimal solution for tap, capacity and power control of OLTC (On-Load Tap Changers), SVR (Step Voltage Regulator), PC (Power Condenser) and DG (Distributed Generation). In the case studies, the estimation and control of the voltages have been testified in a radial distribution system with DG using matlab program.