XML has been become the new standard for publishing and exchanging data on the Web. However, most business data is still stored and maintained in relational database management systems. As such, there is an increasing need to efficiently publish relational data as XML data for Internet-based applications. The most important issue in the transformation is to reflect structural and semantic relations of RDB to XML schema exactly. Most transformation approaches have been done to resolve the issue, but those methods have several problems. In this paper, we discuss algorithm in transforming a relational database schema into corresponding XML schema in XML Schema. We aim to achieve not only explicit/implicit referential integrity relation information but also high level of nested structure while introducing no data redundancy for the transformed XML schema. To achieve these goals, we propose a transformation model which is redundancy free and then we improve the XML Schema structure by exploring more nested structure.