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Modification of Epoxy Resin with Polyether-grafted-Polysiloxane and Epoxy-Miscible Polysiloxane Particles
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  • Modification of Epoxy Resin with Polyether-grafted-Polysiloxane and Epoxy-Miscible Polysiloxane Particles
  • Modification of Epoxy Resin with Polyether-grafted-Polysiloxane and Epoxy-Miscible Polysiloxane Particles
저자명
Ma. Songqi,Liu. Weiqu,Yu. Dan,Wang. Zhengfang
간행물명
Macromolecular research
권/호정보
2010년|18권 1호|pp.22-28 (7 pages)
발행정보
한국고분자학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Polyether-grafted-polysiloxane (FPMS) and epoxy-miscible polysiloxane particles (EMPP) were prepared to improve the toughness of epoxy resin. The chemical structures of the products were characterized by FTIR, $^1H$ NMR, $^{29}Si$ NMR, and gel permeation chromatography (GPC). The morphology of the EMPP was analyzed by transmission electron microscopy (TEM). The thermal and mechanical properties and morphologies of the polysiloxanes modified epoxy networks were examined by differential scanning calorimetry (DSC), tensile and impact testing, and scanning electron microscopy (SEM). Microspheres were observed in the EMPP modified epoxy network, whereas irregular particles were obtained for the FPMS modified epoxy resin. The FPMS and EMPP effectively improved the tensile and impact strength of the cured epoxies, while the glass transition temperatures ($T_gs$) were depressed slightly. Moreover, with the same content of modifiers, the EMPP-modified epoxy network exhibited higher impact strength and lower $T_gs$ than the FPMS-modified epoxy network.