This experimental study investigates the wear resistance improvement in En 52 and 21-4N valve steels through shallow and deep cryogenic treatment using a reciprocatory friction and wear monitor as per the ASTM standard G-133. It has been observed that the wear resistance of En 52 and 21-4N has improved by 81.15% & 13.49% respectively, due to shallow cryogenic treatment, 86.54% & 22.08% respectively, due to deep cryogenic treatment, when compared to the conventional heat treatment. The microstructural study suggests that the improvement in wear resistance and hardness is attributed to the conversion of retained austenite into martensite, along with precipitation and distribution of the carbides brought in by the cryogenic treatment.