In this study, an analysis of evaporative diesel spray and an usefulness of a general-purpose program, ANSYS CFX release 11.0, are investigated through the comparison and investigation of the experimental results carried out under an evaporative field, in which there is phase transition, by an exciplex fluorescence method and the results analyzed by the CFX program. The diesel fuel called n-Tridecane, $C_{13}H_{28}$, is injected from a single-hole nozzle (l/d=1.0mm/0.2mm) into a constant volume chamber under a high temperature and pressure. In the same condition as the experimental condition, the analysis was carried out. Both results of the spray tip penetration were almost coincident at each time. The results have validated the usefulness of this analysis. As a result, if the ambient pressure is high, the spray tip penetration will be shortened and move toward the nozzle exit.