A fire disaster is very serious in the closing space like subway station. In this study, the simulation on fire diffusion is performed to get the temperature history curve, which is used for the fire resisting structural analysis. Most of subway stations are built by the reinforced concrete structure, but recently steel structures are selected for the larger space or beauty. Steel structures relatively have more weaknesses against fire, so it is necessary to develop the method for evaluating fire-resisting capacity in this kind of structures. The developed method is applied to the subway station in Daegu city. It shows that the developed method can be used to simulate the fire disaster and to get the temperature history curve and evaluate the safety of steel structures against the fire.