This treatise analyzed the risk of propylene transported by railroad through quantitative analysis. As a result of survey on propylene transportation route, Iksan station, Suncheon station and Jeonju station were selected as object regions those were expected to have high accident risks. This treatise deduced the scenario of accident and the occurrence rate in accordance with the type of accident possibly to be happening during propylene transportation through ETA( Event Tree Analysis), and expressed the level of personal, social risks after calculating the level of demage influencing over surroundings based on the evaluation for the expected accident damage through PHAST 6.53.