The necessity for harmonically growing of economy and environment has been on the rise late in the twentieth century. Green transformation is defined as efficiency enhancement of conventional guns and ammunitions. We also define green innovation as evolution of fire power systems breaking with conventional methodology. This kind of green innovation could even change a paradigm of warfare in the future. In this paper, we classify the green technology in the field of fire power into five technological groups, and the research and development trend of green technology in the field of fire power is analyzed.