A non-intrusive measurement, Planar Laser Induced Fluorescence was employed to visualize and measure the fuel distribution of the non-reacting field at the burner exit of gas turbine combustor. Measurement techniques, image processing method and quantification procedure were presented. Also, concentration measurement with gas analyzer was carried out to verify the propriety of PLIF result. The PLIF result coincides well with gas analyzer measurement result. PLIF test result for several other conditions are mentioned as well.