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Role of Dispersion State of Ti Species in Deactivation of $MgCl_2$-Supported Ziegler-Natta Catalysts
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  • Role of Dispersion State of Ti Species in Deactivation of $MgCl_2$-Supported Ziegler-Natta Catalysts
  • Role of Dispersion State of Ti Species in Deactivation of $MgCl_2$-Supported Ziegler-Natta Catalysts
저자명
Taniike. Toshiaki,Wada. Toru,Kouzai. Iku,Takahashi. Shougo,Terano. Minoru
간행물명
Macromolecular research
권/호정보
2010년|18권 9호|pp.839-844 (6 pages)
발행정보
한국고분자학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The deactivation behaviors of $TiCl_3/MgCl_2$ model catalysts with molecularly dispersed $TiCl_3$ were investigated to clarify the role of the dispersion state of the Ti species in the deactivation of $MgCl_2$-supported Ziegler-Natta (ZN) catalysts for propylene and ethylene polymerization. The propylene and ethylene polymerization activities of clustered Ti species supported on $MgCl_2$ were approximately one tenth of those of isolated Ti species, which is indicative of the significance of the aggregation of Ti species in the deactivation of ZN catalysts for olefin polymerization. Moreover, the time-course depression of monomer consumption for the clustered Ti species was slower than that for the isolated Ti species in propylene polymerization, whereas the dispersion state barely affected the depression rate in ethylene polymerization. The reduction rate of the Ti species was concluded to be important for the time-course depression of propylene consumption, whereas ethylene polymerization was insensitive to the oxidation state of the Ti species.