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Crystallization of Syndiotactic Polystyrene under High Pressure and Cooling Rate
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  • Crystallization of Syndiotactic Polystyrene under High Pressure and Cooling Rate
  • Crystallization of Syndiotactic Polystyrene under High Pressure and Cooling Rate
저자명
Sorrentino. A.,Pantani. R.,Titomanlio. G.
간행물명
Macromolecular research
권/호정보
2010년|18권 11호|pp.1045-1052 (8 pages)
발행정보
한국고분자학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

This study examined the effect of both pressure and cooling rate on crystallization kinetics of syndiotactic polystyrene (sPS). To that purpose, a homemade apparatus that can solidify polymer samples under cooling rates and pressures comparable to those achieved in common industrial processes, was employed. The morphology of the solidified samples was analyzed by pressure, volume, and temperature (PVT) test, densitometry, infrared (IR) spectroscopy, and X-ray diffraction. The results showed that the overall final crystallinity degree gradually decreases with increasing cooling rate, whereas the kinetics of the ${alpha}$ and ${eta}$ forms are influenced in different ways by the pressure. A Kolmogoroff-Avrami-Evans kinetics model based on a modified Hoffman-Lauritzen approach was introduced for the description of the pressure effects. The results showed a good agreement between the experimental data and model prediction in all ranges of conditions investigated.