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Synthesis and Electrochemical Properties of Ion Exchange Membrane Based on Crosslinked Styrene-(2-hydroxyethyl acrylate)-Lauryl Methacrylate Copolymer
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  • Synthesis and Electrochemical Properties of Ion Exchange Membrane Based on Crosslinked Styrene-(2-hydroxyethyl acrylate)-Lauryl Methacrylate Copolymer
  • Synthesis and Electrochemical Properties of Ion Exchange Membrane Based on Crosslinked Styrene-(2-hydroxyethyl acrylate)-Lauryl Methacrylate Copolymer
저자명
Choi. Eun-Mi,Shin. Kyoung-Sub,Hwang. Taek-Sung
간행물명
Macromolecular research
권/호정보
2010년|18권 12호|pp.1209-1217 (9 pages)
발행정보
한국고분자학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The copolymer, Sty-HEA-LMA, was synthesized by solution polymerization based on styrene (Sty), 2-hydroxyethyl acrylate (HEA), and lauryl methacrylate (LMA). The synthesized copolymer was crosslinked with sulfosuccinic acid (SSA) and glutar aldehyde (GA) via esterification. The sulfonation reaction was performed to introduce sulfonic groups into the membrane with sulfuric acid as the sulfonating agent. The chemical structures of the membranes were characterized by Fourier transform infrared spectroscopy (FTIR) and proton nuclear magnetic resonance spectroscopy ($^1H$ NMR), respectively. The basic membrane properties, such as the water uptake, ion exchange capacity (IEC), ion transport number and electrical properties, were measured for the prepared ion exchange membranes. The IEC value and electrical conductivity increased with increasing sulfonation time due to the ionic group ($-SO_3H$), and were in the range of 0.31-1.15 meq/g and $0.5{ imes}10^{-4}-0.1S/cm$, respectively.