- 지르코니아 첨가된 보로실리케이트 유리의 결정화
- ㆍ 저자명
- 심규인,김영환,임재민,최세영,Shim. Gyu-In,Kim. Young-Hwan,Lim. Jae-Min,Choi. Se-Young
- ㆍ 간행물명
- 韓國軍事科學技術學會誌
- ㆍ 권/호정보
- 2010년|13권 6호|pp.1127-1132 (6 pages)
- ㆍ 발행정보
- 한국군사과학기술학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
Borosilicate glass was prepared in the composition of 81% $SiO_2$, 4% $Na_2O$, 2% $Al_2O_3$, 13% $B_2O_3$. The albite phase($NaAlSi_3O_8$) increased with the $ZrO_2$(0~10wt.%) addition. For measurement of glass transition temperature($T_g$), crystallization temperature($T_{c,max}$) measured by differential thermal analysis. The $T_g$ and $T_{c,max}$ were $510{sim}530^{circ}C$ $650{sim}670^{circ}C$, respectively. The crystallized glass was heated at various conditions(temperature, time). After nucleation at $550^{circ}C$ for 2hours prior to crystal growth at $650^{circ}C$ for 4hours, the resulting Vickers hardness, fracture toughness and bending strength were about $736H_v$, $1.0779MPa{cdot}m^{1/2}$, and 493MPa, which were 17%, 45% and 149% higher than parent borosilicate glass, respectively. Crystal size and transmittance of crystallized borosilicate glass were analyzed by FE-SEM, EDX and UV-VIS-NIR spectrophotometer. Transmittance of crystallized borosilicate glass was decreased with increasing $ZrO_2$(wt%) at visible-range. The results prove that light-weight bulletproof can be fabricated by the crystallization of borosilicate glass.