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Effects of Halide Anions to Absorb SO2 in Ionic Liquids
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  • Effects of Halide Anions to Absorb SO2 in Ionic Liquids
  • Effects of Halide Anions to Absorb SO2 in Ionic Liquids
저자명
Lee. Ki-Young,Kim. Chang-Soo,Kim. Hong-Gon,Cheong. Min-Serk,Mukherjee. Deb Kumar,Jung. Kwang-Deog
간행물명
Bulletin of the Korean Chemical Society
권/호정보
2010년|31권 7호|pp.1937-1940 (4 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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Ionic liquids with halide anions were prepared and the dependency of halide anions on the $SO_2$ solubility of ILs was investigated. The study shows that the $SO_2$ solubility of ionic liquids lies in the range 1.91~2.22 $SO_2$/ILs mol ratio. $SO_2$ solubility in ionic liquids with varying halide anions follows the order Br > Cl > I. Theoretical investigation was also conducted at the B3LYP level using the Gaussian 03 program. From the theoretical consideration of the interaction between $SO_2$ and [EMIm]X (where X = Cl, Br, and I), it has been proposed that primary interaction of halide occurs with $C_2$-H of the imidazolium and S of $SO_2$. Experimental results further shows that the absorption and desorption process of $SO_2$ in ILs was reversible by the three cycles of the absorption at $50^{circ}C$ and desorption at $140^{circ}C$. The reversibility of $SO_2$ absorption was confirmed by FT-IR studies.