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무전해 코발트 코팅된 금속계 SOFC분리판의 제조 및 특성 평가
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  • 무전해 코발트 코팅된 금속계 SOFC분리판의 제조 및 특성 평가
저자명
한원규,주정운,황길호,서현석,신정철,전재호,강성군,Han. Won-Kyu,Ju. Jeong-Woon,Hwang. Gil-Ho,Seo. Hyun-Seok,Shin. Jung-Chul,Jun. Jae-Ho,Kang. Sung-Goon
간행물명
한국재료학회지
권/호정보
2010년|20권 7호|pp.356-363 (8 pages)
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한국재료학회
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정기간행물|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
서지반출

기타언어초록

For this paper, we investigated the area specific resistance (ASR) of commercially available ferritic stainless steels with different chemical compositions for use as solid oxide fuel cells (SOFC) interconnect. After 430h of oxidation, the STS446M alloy demonstrated excellent oxidation resistance and low ASR, of approximately 40 $m{Omega}cm^2$, of the thermally grown oxide scale, compared to those of other stainless steels. The reason for the low ASR is that the contact resistance between the Pt paste and the oxide scale is reduced due to the plate-like shape of the $Cr_2O_3$(s). However, the acceptable ASR level is considered to be below 100 $m{Omega}cm^2$ after 40,000 h of use. To further improve the electrical conductivity of the thermally grown oxide on stainless steels, the Co layer was deposited on the stainless steel by means of an electroless deposition method; it was then thermally oxidized to obtain the $Co_3O_4$ layer, which is a highly conductive layer. With the increase of the Co coating thickness, the ASR value decreased. For Co deposited STS444 with 2 ${mu}m$hickness, the measured ASR at $800^{circ}$ after 300 h oxidation is around 10 $m{Omega}cm^2$, which is lower than that of the STS446M, which alloy has a lower ASR value than that of the non-coated STS. The reason for this improved high temperature conductivity seems to be that the Mn is efficiently diffused into the coating layer, which diffusion formed the highly conductive (Mn,Co)$_3O_4$ spinel phases and the thickness of the $Cr_2O_3$(S), which is the rate controlling layer of the electrical conductivity in the SOFC environment and is very thin