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메탄 부분산화반응 Ni/$CeO_2$ 촉매에 LA 첨가의 영향
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  • 메탄 부분산화반응 Ni/$CeO_2$ 촉매에 LA 첨가의 영향
  • Effects of La addition to Ni/$CeO_2$ Methane Partial Oxidation Catalysts
저자명
천한진,신기석,안성환,윤철훈,함현식,Cheon. Han-Jin,Shin. Ki-Seok,Ahn. Sung-Hwan,Yoon. Cheol-Hun,Hahm. Hyun-Sik
간행물명
한국유화학회지
권/호정보
2010년|27권 1호|pp.29-36 (8 pages)
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한국유화학회
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정기간행물|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The effects of La addition to Ni/$CeO_2$ methane partial oxidation catalysts were investigated. Catalysts were prepared by the impregnation and urea methods. In the preparation of catalysts, La content was changed from 1 wt% to 3wt%. Catalysts that contain 2wt% La showed the highest methane conversion of about 80% and CO selectivity of 84% and $H_2$ selectivity of 70%. This result may be stemmed from that, when La content is 2wt%, a fluorite oxide-type structure is well formed and carbon deposition is also decreased. Among the catalysts, 2.5wt% Ni/Ce(La)Ox showed the highest catalytic activity. From the experiment of changing reaction temperature with 2.5wt% Ni/Ce(La)Ox catalyst, it was found that the optimum reaction temperature is $750^{circ}C$ and at this temperature methane conversion was about 90%, CO and $H_2$ selectivities were 94 and 80%, respectively.