A preliminary thermal analysis is performed for the optical payload system of a geostationary satellite. The optical payload considered in this paper is GOCI(Geostationary Ocean Color Imager) of COMS of Korea. The radiative and conductive thermal models are employed in order to predict thermal responses of the GOCI on the geostationary orbit. The results of this analysis are as follows: 1) the GOCI instrument thermal control is satisfactory to provide the temperatures for the GOCI performances, 2) the thermal control is defined and interfaces are validated, and 3) the entrance baffle temperature and shutter wheel motor gradient are found slightly out their specification, therefore further detailed analyses should be continued on these elements.