During recent years, various studies have demonstrated that indoor chemical pollution causes health problem and also negatively affect the performance of work by occupants. Building materials have been concerned as indoor chemical sources. Some of guidelines and certification system has been developed and resulted as dramatic decrease of harmful indoor chemicals such as formaldehyde and volatile organic compounds. Also, Home furniture and electrical devices has been concerned as one the primary influence the indoor chemical concentration in residential spaces. It is found that various kinds of electric home appliances have a significant source of chemical emission in indoor environments. In this study, the methodologies of detecting harmful chemicals from various kinds of products has been developed with large chamber measurement system and suggest some of the evaluation method for the chemicals from the home appliances as TV sets.