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Preparation and Characterization of a Cation Exchange Membrane Using a Styrene-Hydroxyethyl Acrylate-Lauryl Methacrylate Terpolymer
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  • Preparation and Characterization of a Cation Exchange Membrane Using a Styrene-Hydroxyethyl Acrylate-Lauryl Methacrylate Terpolymer
  • Preparation and Characterization of a Cation Exchange Membrane Using a Styrene-Hydroxyethyl Acrylate-Lauryl Methacrylate Terpolymer
저자명
Choi. Eun-Mi,Shin. Kyoung-Sub,Hwang. Taek-Sung
간행물명
Macromolecular research
권/호정보
2010년|18권 6호|pp.577-582 (6 pages)
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한국고분자학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

A novel cation exchange membrane based on a styrene-hydroxy ethyl acrylate-lauryl methacrylate terpolymer (St-HEA-LMA) was prepared. Sulfonic groups were introduced to the membrane structure with sulfuric acid as the sulfonating agent and silver sulfate as the initiator. Sulfonated St-HEA-LMA terpolymer membranes were characterized by Fourier-transform infrared (FTIR) spectroscopy and atomic force microscopy (AFM), as well as by determining the degree of sulfonation (DS), ion-exchange capacity (IEC), swelling ratio and electrical resistance of the membranes. The presence of sulfonic groups in the sulfonated St-HEA-LMA terpolymer was confirmed by FTIR, and the resulting membrane exhibited an ion-exchange capacity of 2.13 meq/g and an electrical resistance of 1.17 $Omega{cdot}cm^2$. The swelling ratio of the prepared membranes increased with increasing degree of sulfonation, and the tensile strength decreased with increasing degree of sulfonation at a reaction temperature of $30^{circ}C$. The phase images obtained by AFM clearly showed an increase in roughness with increasing DS. Considering the mechanical properties, the sulfonated St-HEA-LMA terpolymer obtained at a sulfonation reaction temperature of $20^{circ}C$ was suitable for ion-exchange membrane applications.